RHODIUM CATALYZED TRANSFORMATION OF PROPARGYLAMINES TO 2-SILYLMETHYL-2-ALKENALS - FORMAL SILYLFORMYLATION OF ALLENES

被引：39

作者：

MATSUDA, I ^{[1
]}

SAKAKIBARA, J ^{[1
]}

INOUE, H ^{[1
]}

NAGASHIMA, H ^{[1
]}

机构：

[1] TOYOHASHI UNIV TECHNOL,SCH MAT SCI,TOYOHASHI 441,JAPAN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 39期

关键词：

D O I：

10.1016/0040-4039(92)89035-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Propargylamines are effectively transformed to 2-dimethylphenylsilylmethyl-2-alkenals by the interaction of two equivalents of Me2PhSiH under silylformylation conditions catalyzed by Rh4(CO)12. The products are not obtained directly by silylformylation of the corresponding allenes.

引用

页码：5799 / 5802

页数：4

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