SIMULATION OF GAS-PHASE COLLISION-INDUCED SPECTRA - QUADRUPOLE-INDUCED SPECTRA INCLUDING TERNARY EFFECTS

被引：0
作者：
WEISS, S
机构：
[1] Department of Chemistry, Ben-Gurion University, Beer Sheva
来源：
MOLECULAR PHYSICS | 1991年 / 72卷 / 05期
关键词：
D O I：
10.1080/00268979100100721
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Simulation of collision-induced spectra of gaseous H-2-Ar mixtures at 195 K taking ternary interactions into account are performed. Interactions are assumed to be pairwise additive. The ternary contribution obtained is in qualitative agreement with experimental results. The central part of the simulated lineshapes narrows with density whereas the wings become enhanced. Both these findings are in accord with experimental observations.
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页码：987 / 991
页数：5
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