3RD-ORDER NONLINEAR OPTICAL SUSCEPTIBILITIES OF SOLUTIONS OF SOME MESOGENIC METALLOTETRAPHENYLPORPHYRINS BY NANOSECOND DEGENERATE 4-WAVE MIXING METHOD

被引：22

作者：

SAKAGUCHI, T ^{[1
]}

SHIMIZU, Y ^{[1
]}

MIYA, M ^{[1
]}

FUKUMI, T ^{[1
]}

OHTA, K ^{[1
]}

NAGATA, A ^{[1
]}

机构：

[1] GOVT IND RES INST, DEPT ORGAN MAT, IKEDA, OSAKA 563, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 02期

关键词：

D O I：

10.1246/cl.1992.281

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The benzene solutions of a mesogenic tetraphenylporphyrin, 5,10,15,20-Tetrakis (4-n-pentadecylphenyl)porphyrin, and its metal complexes (metal:Co,Ni,Cu,Zn, and V = O) were investigated to determine the 3rd-order nonlinear optical susceptibilities chi(3) by nanosecond degenerate four-wave mixing (DFWM) at 532 nm. All solutions of approximately the same concentration (almost-equal-to 10(-5) mol/1) showed chi(3)-values of the same order of magnitude, almost-equal-to 10(-11) esu.

引用

页码：281 / 284

页数：4

共 9 条

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