ELECTROLYTE-SOLVENT INTERACTION IN THE DIPOLAR APROTIC-SOLVENT DIMETHYLSULFOXIDE AT 25-DEGREES-C

被引：5
|
作者：
HAFEZ, AM
RAMADAN, MS
SADEK, H
机构：
[1] Alexandria Univ, Chemistry Dep,, Alexandria, Egypt, Alexandria Univ, Chemistry Dep, Alexandria, Egypt
来源：
ELECTROCHIMICA ACTA | 1985年 / 30卷 / 12期
关键词：
ELECTROCHEMISTRY; -; SOLUTIONS; SOLVENTS;
D O I：
10.1016/0013-4686(85)87018-3
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Conductance measurements are reported for s-alkylisothiouronium bromide, iodide and picrate salts in the dipolar aprotic solvent DMSO at 25 degree C. The data were analysed by R. M. Fuoss's equation for 1:1 electrolytes, from which the values of LAMBDA //0, the Gurney's cosphere diameter R and K//A are obtained. The results are discussed in the light of the recorded values of the constants K//R and K//S and the free energy term G//s.
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页码：1711 / 1714
页数：4
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