THE RE-RE BOND IN BINUCLEAR DI-MU-OXORHENIUM COMPLEXES CONTAINING THE 1,4,7-TRIAZACYCLONONANE LIGAND

被引：30

作者：

BOHM, G

WIEGHARDT, K

NUBER, B

WEISS, J

机构：

[1] RUHR UNIV BOCHUM,LEHRSTUHL ANORGAN CHEM 1,POSTFACH 102148,W-4630 BOCHUM,GERMANY

[2] UNIV HEIDELBERG,INST ANORGAN CHEM,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 07期

关键词：

D O I：

10.1002/anie.199007871

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ReRe double bonds characterize complexes 1 and 2. Complex 3 contains a triple bond. In all cases, the Re2O2 rings are planar. Comparison of these complexes with the Cp* analogue 4 does not answer the question why 4 exhibits no ReRe bond. L = 1,4,7‐triazacyclononane. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

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页码：787 / 790

页数：4

相关论文

共 26 条

[1]

ARZOUMANIAN H, 1985, J ORGANOMET CHEM, V294, P357

[2] CRYSTAL-STRUCTURE OF DOUBLE RHENIUM OXIDES .2. LANTHANUM RHENIUM OXIDE [J].

BESSE, JP ;

BAUD, G ;

CHEVALIER, R ;

GASPERIN, M .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (DEC) :3532-3535

[3]

BURGI HB, 1981, INORG CHEM, V20, P3829

[4] ELECTRONIC-STRUCTURE OF PIANO-STOOL DIMERS .8. ELECTRONICALLY INDUCED CONFORMATIONAL-CHANGES IN HIGH-VALENT BIMETALLIC CHALCOGEN COMPLEXES OF THE TYPE [CPML]2(MU-L)2(M = MO, RE - L = S, O) [J].

BURSTEN, BE ;

CAYTON, RH .

INORGANIC CHEMISTRY, 1989, 28 (14) :2846-2853

[5] MONONUCLEAR + POLYNUCLEAR CHEMISTRY OF RHENIUM (3) - ITS PRONOUNCED HOMOPHILICITY [J].

COTTON, FA ;

CURTIS, NF ;

JOHNSON, BFG ;

MAGUE, JT ;

WOOD, JS ;

HARRIS, CB ;

ROBINSON, WR ;

LIPPARD, SJ .

SCIENCE, 1964, 145 (363) :1305-&

[6] THE STRUCTURES OF METAL METAL-BONDED EDGE-SHARING BIOCTAHEDRAL COMPLEXES [J].

COTTON, FA .

POLYHEDRON, 1987, 6 (04) :667-677

[7]

COTTON FA, 1981, MULTIPLE BONDS METAL

[8]

Herrmann W.A., 1984, ANGEW CHEM, V96, P364

[9] MULTIPLE BONDS BETWEEN PRINCIPAL GROUP ELEMENTS AND TRANSITION-METALS .7. OXIDATIVE DECARBONIZATION PROCESSES IN PHOTOCHEMISTRY OF TRICARBONYL(ETA-5-PENTAMETHYLCYCLOPENTADIENYL)RHENIUM - NEW OXO-RHENIUM COMPLEXES [J].

HERRMANN, WA ;

SERRANO, R ;

SCHAFER, A ;

KUSTHARDT, U ;

ZIEGLER, ML ;

GUGGOLZ, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 272 (01) :55-71

[10] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .43. SYNTHESIS AND STRUCTURE OF KEY ORGANORHENIUM OXIDES AND HALIDES OF THE PI-AROMATIC SERIES [J].

HERRMANN, WA ;

FLOEL, M ;

KULPE, J ;

FELIXBERGER, JK ;

HERDTWECK, E .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 355 (1-3) :297-313