DEGRADATION OF ORGANOPHOSPHONIC ACIDS CATALYZED BY IRRADIATED TITANIUM-DIOXIDE

被引：28

作者：

KROSLEY, KW ^{[1
]}

COLLARD, DM ^{[1
]}

ADAMSON, J ^{[1
]}

FOX, MA ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1993年 / 69卷 / 03期

关键词：

D O I：

10.1016/1010-6030(93)85103-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The photoinduced decomposition of three organic phosphonic acids -on irradiated titanium dioxide involves the cleavage of the carbon-phosphorus bond to generate the corresponding organic radical. Kinetic data for these reactions are consistent with the Langmuir-Hinshelwood model for heterogeneous reactions.

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页码：357 / 360

页数：4

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