THE SYNTHESIS AND PROPERTIES OF HETERODINUCLEAR ALKANEDIYL COMPLEXES OF IRON(II) CONTAINING MOLYBDENUM(II), TUNGSTEN(II), RHENIUM(I) AND RUTHENIUM(II)

被引：24

作者：

FRIEDRICH, HB ^{[1
]}

MOSS, JR ^{[1
]}

WILLIAMSON, BK ^{[1
]}

机构：

[1] UNIV CAPE TOWN,DEPT CHEM,RONDEBOSCH 7700,SOUTH AFRICA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 394卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(90)87241-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of the iodoalkyl compounds [(η5-C5R5)Fe(CO)2{(CH2)nI}] with Na[MLy] yield the new heterodinuclear alkanediyl compounds [(η5-C5R5)-(CO)2Fe(CH2)nMLy] (where R = H: MLy = Mo(CO)3Cp, W(CO)3Cp, Re(CO)5, n = 3-6; R = CH3: MLy = Ru(CO)2Cp, n = 3-5; Re(CO)5, n = 4). The related mixed ligand complex [Cp(CO)2Fe(CH2)3Fe(CO)2CP{black star}] has also been prepared (where Cp = η5-C5H5 and Cp{black star} = η5-C5(CH3)5). The new compounds have been fully characterised by analytical and spectroscopic methods. © 1990.

引用

页码：313 / 327

页数：15

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