BICYCLOCALIX[4]ARENES

被引：19
作者：
BERGER, B
BOHMER, V
PAULUS, E
RODRIGUEZ, A
VOGT, W
机构：
[1] UNIV MAINZ,INST ORGAN CHEM,JJ BECHERWEG 34,SB1,W-6500 MAINZ,GERMANY
[2] HOECHST AG,W-6230 FRANKFURT,GERMANY
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 01期
关键词：
D O I：
10.1002/anie.199200961
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The construction of a macrobicycle from three calix[4]arene units as in 2 can be achieved by a double aldol condensation of 1, a nitromalonaldehyde with a bridging ketone unit. In the crystal the newly formed nitrophenol unit is virtually parallel to one of the nonbridged phenol units; in solution it swings in the cavity of the calix[4]arene A-B-C-D like the clapper of a bell. R = cyclo-C6H11.
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页码：96 / 99
页数：4
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