CATIONIC COMPLEXES OF DIORGANOTIN(IV) DERIVATIVES - THE CRYSTAL-STRUCTURE OF TETRAKIS[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIETHYLTIN(IV) NITRATE

被引：13
作者：
CASAS, JS
MARTINEZ, EG
GONZALEZ, AS
SORDO, J
CASELLATO, U
GRAZIANI, R
RUSSO, U
机构：
[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN
[2] CNR,IST CHIM & TECNOL RADIOELEMENTI,PADUA,ITALY
[3] UNIV PADUA,DIPARTIMENTO CHIM INORGAN METALLORGAN & ANALI,I-35131 PADUA,ITALY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期
关键词：
TIN; X-RAY STRUCTURE; DIETHYLTIN COMPLEX;
D O I：
10.1016/0022-328X(94)05302-R
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[SnEt(2)(Hmimt)(4)](NO3)(2) (Hmimt = 1-methyl-2(3H)-imidazolinethione) has been synthesized and characterized by mass spectrometry, IR, Raman, Mossbauer, H-1, C-13 and Sn-119 NMR spectroscopy, and its crystal structure determined by X-ray crystallography. The coordination distances in the centrosymmetric octahedral cation are 2.163(5) Angstrom for Sn-C, and 2.729(2) and 2.752(2) Angstrom for Sn-S, and the [SnEt(2)(Hmimt)(4)](NO3)(2) units are interconnected by hydrogen bonds via their nitrate ions.
引用
收藏
页码：107 / 111
页数：5
相关论文
共 18 条
[11]   ORGANOTIN COMPOUNDS WITH 1-METHYL-2(3 H)-IMIDAZOLINETHIONE - THE CRYSTAL AND MOLECULAR-STRUCTURE OF DICHLOROBIS[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIPHENYLTIN(IV) [J].
MARTINEZ, EG ;
GONZALEZ, AS ;
CASAS, JS ;
SORDO, J ;
CASELLATO, U ;
GRAZIANI, R ;
RUSSO, U .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 463 (1-2) :91-96
[12]   ORGANOTIN COMPLEXES WITH 1-METHYL-2(3H)-IMIDAZOLINETHIONE - THE CRYSTAL-STRUCTURE OF DICHLORO[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIMETHYLTIN(IV) [J].
MARTINEZ, EG ;
GONZALEZ, AS ;
CASAS, JS ;
SORDO, J ;
VALLE, G ;
RUSSO, U .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 453 (01) :47-52
[13]  
MARTINEZ EG, 1994, THESIS U SANTIAGO CO
[14]   A SEMI-EMPIRICAL METHOD OF ABSORPTION CORRECTION [J].
NORTH, ACT ;
PHILLIPS, DC ;
MATHEWS, FS .
ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1968, A 24 :351-&
[15]   PREPARATION, CHARACTERIZATION AND CRYSTAL-STRUCTURE OF DICHLORO TETRAKIS-(1-METHYLIMIDAZOLINE-2(3H)-THIONE) PLATINUM(II) DIHYDERATE [J].
ONEILL, ME ;
RAPER, ES ;
DANIELS, JA ;
NOWELL, IW .
INORGANICA CHIMICA ACTA-BIOINORGANIC CHEMISTRY, 1982, 66 (03) :79-84
[16]   IRON(II) COMPLEXES OF IMIDAZOLINE-2-THIONES - THE CRYSTAL-STRUCTURE OF DICHLOROBIS(1-METHYLIMIDAZOLINE-2-THIONE)IRON(II) [J].
RAPER, ES ;
CARTY, P ;
CREIGHTON, JR ;
MILLER, A ;
CLEGG, W .
TRANSITION METAL CHEMISTRY, 1988, 13 (05) :356-360
[17]   1-METHYL-4-IMIDAZOLINE-2-THIONE - STRUCTURE, COMPARISON WITH RELATED MOLECULES AND A DISCUSSION OF COORDINATION CHARACTERISTICS [J].
RAPER, ES ;
CREIGHTON, JR ;
OUGHTRED, RE ;
NOWELL, IW .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1983, 39 (JUN) :355-360
[18]  
SHELDRICK GM, 1980, SHELX PROGRAM CRYSTA
12