CATIONIC COMPLEXES OF DIORGANOTIN(IV) DERIVATIVES - THE CRYSTAL-STRUCTURE OF TETRAKIS[1-METHYL-2(3H)-IMIDAZOLINETHIONE]DIETHYLTIN(IV) NITRATE

被引：13

作者：

CASAS, JS

MARTINEZ, EG

GONZALEZ, AS

SORDO, J

CASELLATO, U

GRAZIANI, R

RUSSO, U

机构：

[1] UNIV SANTIAGO DE COMPOSTELA,DEPT QUIM INORGAN,E-15706 SANTIAGO,SPAIN

[2] CNR,IST CHIM & TECNOL RADIOELEMENTI,PADUA,ITALY

[3] UNIV PADUA,DIPARTIMENTO CHIM INORGAN METALLORGAN & ANALI,I-35131 PADUA,ITALY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

TIN; X-RAY STRUCTURE; DIETHYLTIN COMPLEX;

D O I：

10.1016/0022-328X(94)05302-R

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[SnEt(2)(Hmimt)(4)](NO3)(2) (Hmimt = 1-methyl-2(3H)-imidazolinethione) has been synthesized and characterized by mass spectrometry, IR, Raman, Mossbauer, H-1, C-13 and Sn-119 NMR spectroscopy, and its crystal structure determined by X-ray crystallography. The coordination distances in the centrosymmetric octahedral cation are 2.163(5) Angstrom for Sn-C, and 2.729(2) and 2.752(2) Angstrom for Sn-S, and the [SnEt(2)(Hmimt)(4)](NO3)(2) units are interconnected by hydrogen bonds via their nitrate ions.

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收藏

页码：107 / 111

页数：5

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