A HIGHLY CATALYTIC AND SELECTIVE CONVERSION OF CARBOXYLIC-ACIDS TO 1-ALKENES OF ONE LESS CARBON-ATOM

被引：76

作者：

MILLER, JA ^{[1
]}

NELSON, JA ^{[1
]}

BYRNE, MP ^{[1
]}

机构：

[1] HENKEL RES CORP,SANTA ROSA,CA 95407

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 01期

关键词：

D O I：

10.1021/jo00053a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An equimolar mixture of a carboxylic acid and acetic anhydride produces a reagent combination that undergoes a highly efficient decarbonylation/dehydration at 250-degrees-C using either Pd- or Rh-based catalyst systems, affording excellent yields of the corresponding 1-alkenes of one less carbon atom.

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页码：18 / 20

页数：3

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