SYNTHETIC ROUTES TO BUTADIENYL COMPLEXES - DOUBLE ADDITION OF METHYLENE TO AN ACETYLIDE AND HYDROMETALLATION OF AN ENE-YNE - X-RAY CRYSTAL-STRUCTURE OF [FE2(CO)5(MU-ETA-2,ETA-3-H2C=C(ME)C=CH2)(MU-PPH2)]

被引：20

作者：

BRECKENRIDGE, SM ^{[1
]}

MACLAUGHLIN, SA ^{[1
]}

TAYLOR, NJ ^{[1
]}

CARTY, AJ ^{[1
]}

机构：

[1] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,DEPT CHEM,WATERLOO CAMPUS,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001718

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Binuclear butadienyl complexes [Fe2(CO)5{mu-eta-2,eta-3-H2C = C(R)C = CH2}(mu-PPH2)] (R = Bu(t), Me) have been synthesized via double addition of CH2 fragments to an acetylide in [Fe2(CO)6(mu-eta-1,eta-2-C = CBut)(mu-PPh2)] or hydrometallation of the ene-yne CH2 = C(Me)C = CH with [HFe2(CO)7(mu-PPh2)].

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页码：1718 / 1720

页数：3

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