INFLUENCE OF ADDITIVES ON THE ELECTRODEPOSITION OF NICKEL FROM A WATTS BATH - A CYCLIC VOLTAMMETRIC STUDY

被引：86

作者：

MIMANI, T

MAYANNA, SM

MUNICHANDRAIAH, N

机构：

[1] BANGALORE UNIV,COLL CENT,BANGALORE 560001,KARNATAKA,INDIA

[2] AFSC,WRIGHT LAB,DIV AEROSP & POWER,WRIGHT PATTERSON AFB,OH

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1993年 / 23卷 / 04期

关键词：

D O I：

10.1007/BF00296689

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical reactions occurring during the deposition of nickel from a Watts bath have been examined using a voltammetric technique. The important reactions taking place at the anode and cathode have been systematically identified. The influence of the additives on the cathodic and anodic reactions show the importance of careful bath preparation for a quality controlled product. From the surface coverage data, the free energy change (DELTAG(a)0) for the adsorption of the brighteners has been calculated and compared with results from methods used earlier.

引用

页码：339 / 345

页数：7

共 18 条

[1] A VOLTAMMETRIC STUDY OF THE ELECTRODEPOSITION CHEMISTRY IN THE FE-S SYSTEM [J].

ARICO, AS ;

ANTONUCCI, V ;

ANTONUCCI, PL ;

COCKE, DL ;

GIORDANO, N .

ELECTROCHIMICA ACTA, 1991, 36 (3-4) :581-590

[2]

BELLAVANCE MI, 1975, ENCY ELECTROCHEMISTR, V2, P2

[3]

Brown H., 1974, MODERN ELECTROPLATIN, P287

[4]

COTTON FA, 1972, ADV INORGANIC CHEM 2, P239

[5]

Elder J.P., 1962, ELECTROCHIM ACTA, V7, P417, DOI [10.1016/0013-4686(62)80030-9, DOI 10.1016/0013-4686(62)80030-9]

[6]

FRUMKIN A, 1958, Z ELEKTROCHEM, V62, P251

[7]

GRECHEV T, 1991, ELECTROCHIM ACTA, V36, P1315

[8]

GREEF R, 1985, INSTRUMENTAL METHODS, P359

[9]

HOAR TP, 1953, T I MET FINISH, V29, P302

[10] BORIC-ACID AS A CATALYST IN NICKEL PLATING SOLUTIONS [J].

HOARE, JP .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (12) :3102-3103

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