1ST GAS-PHASE SPECTRUM OF THE ALUMINUM CARBIDE MOLECULE - THE B4-SIGMA--X4-SIGMA-SYSTEM

被引：51

作者：

BRAZIER, CR

机构：

[1] Phillips Laboratory/RKFE, Edwards Air Force Base

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 98卷 / 04期

关键词：

D O I：

10.1063/1.464160

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The aluminum carbide radical has been seen in the gas phase for the first time. The B 4SIGMA-X 4SIGMA- system near 22 000 cm-1 was observed in emission from a hollow cathode source. Three vibrational sequences were detected: DULTAv = 0, -1, and -2, and a full rotational analysis was performed on the five strongest bands, 0-0, 1-1, 0-1, 1-2, and 2-3.

引用

收藏

页码：2790 / 2797

页数：8

相关论文

共 8 条

[1] THE COMPUTED SPECTRUM OF ALC [J].

BAUSCHLICHER, CW ;

LANGHOFF, SR ;

PETTERSSON, LGM .

JOURNAL OF CHEMICAL PHYSICS, 1988, 89 (09) :5747-5752

[2]

BRAZIER CR, UNPUB

[3]

CARRICK PG, 1992, P HIGH ENERGY DENSIT

[4] The energy levels of a rotating vibrator [J].

Dunham, JL .

PHYSICAL REVIEW, 1932, 41 (06) :721-731

[5] ANOMALIES IN THE ROTATIONAL STRUCTURE OF THE OPTICAL-SPECTRUM OF NBO - EVIDENCE FOR CASE(A) COUPLING IN THE 4-SIGMA-GROUND STATE [J].

FEMENIAS, JL ;

CHEVAL, G ;

MERER, AJ ;

SASSENBERG, U .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1987, 124 (02) :348-368

[6] FOURIER-TRANSFORM EMISSION-SPECTROSCOPY - THE B4-SIGMA--X4-SIGMA- TRANSITION OF BC [J].

FERNANDO, WTML ;

OBRIEN, LC ;

BERNATH, PF .

JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (12) :8482-8487

[7] LASER VAPORIZATION GENERATION OF AL12C, AL13C, AL12C2, AND AL13C2 FOR RARE-GAS MATRIX ELECTRON-SPIN-RESONANCE STUDIES - EXPERIMENTAL-THEORETICAL COMPARISONS [J].

KNIGHT, LB ;

COBRANCHI, ST ;

HERLONG, JO ;

ARRINGTON, CA .

JOURNAL OF CHEMICAL PHYSICS, 1990, 92 (10) :5856-5866

[8]

PALMER BA, 1983, LA9615 TECHN REP