OXIDATIVE CLEAVAGE OF TRIETHYLENETETRAMINE (TRIEN) TO YIELD DIETHYLENETRIAMINE (DIEN) - STRUCTURE OF THE MN-II/MN-III HEPTANUCLEAR COMPLEX [MN7(TRIEN)2(DIEN)2O4(OAC)8](PF6)4.2H2O

被引：36
作者：
BHULA, R
WEATHERBURN, DC
机构：
[1] Department of Chemistry, Victoria University of Wellington, Wellington
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 06期
关键词：
D O I：
10.1002/anie.199106881
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two [Mn4(mu-3-O)2] moieties with butterfly structure, which are coupled via a common Mn atom, are present in the cation of the title compound (structure with coordinated N (black-circle) and O atoms (black-circle) shown below). The complex cation, which contains six Mn(III) centers and one Mn(II) center, is formed in the reaction of manganese(III) acetate and triethylenetetramine in methanol. During the reaction a part of the tetramine ligand is cleaved oxidatively with formation of diethylenetriamine.
引用
收藏
页码：688 / 689
页数：2
相关论文
共 50 条
  • [21] Crystal structure of hexaaquabis{2-[N-(4-pyridylcarbonyl)hydrazido]-propionato}dimanganese(II) tetrahydrate, Mn2(H2O)6(C9H7N3O3)2 • 4H2O
    Kong, ZP
    Bao, RL
    Zhou, XG
    Pang, Z
    Jiang, L
    Chen, ZX
    Yue, B
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2005, 220 (01): : 85 - 86
  • [22] Synthesis, structure and magnetic properties of the antiferromagnetic hexamanganese cluster [Mn6(μ4-O)2(O2CC6HF4)10 (HO2CCH3)4]•(C7H8)
    Nakata, K
    Miyasaka, H
    Ishii, T
    Yamashita, M
    Awaga, K
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2002, 379 : 211 - 216
  • [23] Crystal structure of (4-carboxy-2-sulfonatobenzoato-O,O′)-bis-(2,2′-bipyridyl) manganese(II) sesterhydrate, Mn(C10H8N2)2(C8H4O7S)•2.5H2O, C28H25MnN4O9.50S
    Lian, Zhaoxun
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (04): : 477 - 478
  • [24] Crystal structure of bis(2-nitrobenzoato-O)bis(1,10-phenanthroline-N,N′)manganese(II) tetrahydrate, [Mn(C7H4NO4)2(C12H8N2)2] • 4H2O
    Cao, Ye-Xia
    Ding, Li-Yuan
    Yang, Zhi-Meng
    Yin, Ai-Ping
    Liu, Cheng-Qi
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (04): : 453 - 454
  • [25] Crystal structure of tetraaqua-2,2′-bipyridinemanganese(II) 4-(sulfonylglycine)benzoic acid, [Mn(H2O)4(C10H8N2)][C10H7NO6S]
    Zhang, Wen-Ying
    Yuan, Shuai
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (02): : 149 - 151
  • [26] Crystal structure of bis(2,2′-bipyridyl)-hexa[μ-2-(4′-chlorobenzoyl)benzoato-κ2O:O′)trimanganese(II), Mn3(C10H8N2)2(C14H8O3Cl)6
    Li, Xiu-Mei
    Liu, Bo
    Wang, Qing-Wei
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2012, 227 (02): : 158 - 160
  • [27] Crystal structure of (μ2-2,2′-bipyrimidine)-tetrabromotetrakis(N,N-dimethylformamide-κO)dimanganese(II), Mn2Br4(C8H6N4)(C3H7NO)4
    Ha, Kwang
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2011, 226 (02): : 183 - 184
  • [28] Crystal structure of diaquadipimelatobis(1,10-phenanthroline-N,N′)-di[manganese(II), zinc(II)] dihydrate, [(Zn0.7Mn0.3)2(C12H8N2)2(H2O)2(C7H10O4)2] • 2H2O
    Zheng, YQ
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2004, 219 (04): : 427 - 428
  • [29] SYNTHESIS, CRYSTAL-STRUCTURES, REACTIVITY, AND MAGNETOCHEMISTRY OF A SERIES OF BINUCLEAR COMPLEXES OF MANGANESE(II), MANGANESE(III), AND MANGANESE(IV) OF BIOLOGICAL RELEVANCE - THE CRYSTAL-STRUCTURE OF [L'MNIV(MU-O)3MNIVL'](PF6)2.H2O CONTAINING AN UNPRECEDENTED SHORT MN...MN DISTANCE OF 2.296 AS
    WIEGHARDT, K
    BOSSEK, U
    NUBER, B
    WEISS, J
    BONVOISIN, J
    CORBELLA, M
    VITOLS, SE
    GIRERD, JJ
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (22) : 7398 - 7411
  • [30] Crystal structure of diaquabis[1,3-di(4-pyridyl)propane]manganese(II) bis(hydrogen 4-amino-o-phthalate), [Mn(H2O)2(C13H14N2)2](C8H6O4N)2
    Xin, Ling-Yun
    Liu, Guang-Zhen
    Li, Xiao-Ling
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (04): : 739 - 740
12345