THE 1ST OCTAHEDRAL ZINTL ION - SN-6(2-) AS A LIGAND IN [SN6(CR(CO)5)6]2-

被引：57

作者：

SCHIEMENZ, B ^{[1
]}

HUTTNER, G ^{[1
]}

机构：

[1] UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270,W-6900 HEIDELBERG,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not only aesthetically pleasing, anion 1 is chemically significant. Its isolation as a K[2.2.2]cryptand salt shows for the first time that octahedral main group element aggregates such as Sn-6(2-)the first octahedral Zintl ion-can also exist.

引用

页码：297 / 298

页数：2

共 13 条

[1]

[Anonymous], ATOMS POLYM ISOELECT

[2] POLYATOMIC ZINTL ANIONS OF THE POSTTRANSITION ELEMENTS [J].

CORBETT, JD .

CHEMICAL REVIEWS, 1985, 85 (05) :383-397

[3] NONASTANNIDE(4-) ANION SN94-, A NOVEL CAPPED ANTI-PRISMATIC CONFIGURATION (C4V)1 [J].

CORBETT, JD ;

EDWARDS, PA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (10) :3313-3317

[4]

Cotton FA., 1988, ADV INORG CHEM, V5

[5] SYNTHESIS AND STRUCTURE OF CLOSO-SN9CR(CO)34- - THE 1ST MEMBER IN A NEW CLASS OF POLYHEDRAL CLUSTERS [J].

EICHHORN, BW ;

HAUSHALTER, RC ;

PENNINGTON, WT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) :8704-8706

[6]

Greenwood NN, 1984, CHEM ELEMENTS

[7] NAKED MAIN GROUP ELEMENTS AS TRIGONALLY PLANAR BONDED NU-3 BRIDGING LIGANDS [J].

HUTTNER, G ;

WEBER, U ;

SIGWARTH, B ;

SCHEIDSTEGER, O ;

LANG, H ;

ZSOLNAI, L .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 282 (03) :331-348

[8]

KAUZLARICH SM, 1990, COMMENTS INORG CHEM, P75

[9] IMPROVED SYNTHESIS OF (AMINOCARBENE)CHROMIUM(0) COMPLEXES WITH USE OF C8K-GENERATED CR(CO)5(2-) - MULTIVARIANT OPTIMIZATION OF AN ORGANOMETALLIC REACTION [J].

SCHWINDT, MA ;

LEJON, T ;

HEGEDUS, LS .

ORGANOMETALLICS, 1990, 9 (10) :2814-2819

[10] GE-GE BONDING IN THE HIGH-PRESSURE MODIFICATION OF LITHIUM GERMANIDE - A NEAR-ZINTL PHASE [J].

SHERWOOD, P ;

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) :2881-2886

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