SYNTHESES OF 2,9-BIS(HALOMETHYL)-1,10-PHENANTHROLINES - POTENTIAL ROBUST LIGANDS FOR METAL OXIDATION CATALYSTS

被引：33
作者：
BEER, RH [1 ]
JIMENEZ, J [1 ]
DRAGO, RS [1 ]
机构：
[1] UNIV FLORIDA,DEPT CHEM,GAINESVILLE,FL 32611
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 07期
关键词：
D O I：
10.1021/jo00059a024
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known alpha-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines. The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro- and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts.
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页码：1746 / 1747
页数：2
相关论文
共 15 条
[1]  
CHANDLER CJ, 1982, J HETEROCYCLIC CHEM, V19, P599
[2]   STABLE HIGHLY OXIDIZING COBALT COMPLEXES OF MACROCYCLIC LIGANDS [J].
COLLINS, TJ ;
POWELL, RD ;
SLEBODNICK, C ;
UFFELMAN, ES .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (22) :8419-8425
[3]  
GOLDSTEIN A, UNPUB
[4]  
GOLDSTEIN AS, 1991, J CHEM SOC CHEM COMM, P22
[5]  
Hudlicky M., 1976, CHEM ORGANIC FLUORIN
[6]  
LEUNG WH, 1988, J CHEM SOC CHEM COMM, P1406
[7]   SELECTIVE LOW-TEMPERATURE HYDROXYLATION OF ISOBUTANE BY MOLECULAR-OXYGEN CATALYZED BY AN IRON PERHALOPORPHYRIN COMPLEX [J].
LYONS, JE ;
ELLIS, PE .
CATALYSIS LETTERS, 1991, 8 (01) :45-51
[8]  
LYONS JE, 1900, J CATAL LETT, V29, P1028
[9]   ALPHA-METHYL FUNCTIONALIZATION OF ELECTRON-POOR HETEROCYCLES - 2,9-BIS(CHLOROMETHYL)-1,10-PHENANTHROLINE - SYNTHESIS OF A [3.3)CYCLOPHANE CONTAINING THE 1,10-PHENANTHROLINO MOIETY [J].
NEWKOME, GR ;
KIEFER, GE ;
PUCKETT, WE ;
VREELAND, T .
JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (25) :5112-5114
[10]   CHEMISTRY OF HETEROCYCLIC-COMPOUNDS .124. MONO-ALPHA-FUNCTIONALIZATION OF 2,9-DIMETHYL-1,10-PHENANTHROLINE [J].
NEWKOME, GR ;
THERIOT, KJ ;
GUPTA, VK ;
FRONCZEK, FR ;
BAKER, GR .
JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (07) :1766-1769
12