A SYNTHETIC ROUTE FOR THE SYNTHESIS OF STAR-SHAPED MACROMOLECULES

被引：8

作者：

TSITSILIANIS, C

BOULGARIS, D

机构：

[1] Department of Chemical Engineering, University of Patras, Patras

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1995年 / A32卷

关键词：

D O I：

10.1080/10601329508018946

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A multistep synthetic methodology for the synthesis of star-shaped macromolecules is presented. The method relies on sequential anionic living copolymerization, where divinyl-benzene is used as the linking agent. A variety of star-shaped macromolecules such as star homopolymers, A(n), heteroarm star copolymers, A(n)B(n), star block copolymers, (AU)(n), and functionalized star-polymers can be produced. The synthesis characterization and some properties of such polymeric species are reviewed and the advantages as well as the drawbacks of the method are discussed.

引用

页码：569 / 577

页数：9

共 23 条

[1]

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[2]

BYWATER S, 1979, ADV POLYM SCI, V30, P89

[3]

DELACRUZ MO, 1986, MACROMOLECULES, V19, P2501

[4] STAR POLYMERS FROM STYRENE AND DIVINYLBENZENE [J].