PULSE-RADIOLYSIS OF SOME AROMATIC SULFOXIDES IN AQUEOUS-SOLUTIONS

被引：0

作者：

KISHORE, K

DEY, GR

MOORTHY, PN

机构：

来源：

PROCEEDINGS OF THE INDIAN ACADEMY OF SCIENCES-CHEMICAL SCIENCES | 1993年 / 105卷 / 02期

关键词：

PULSE RADIOLYSIS; AROMATIC SULFOXIDES; TRANSIENTS;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of e(aq)- and H-atoms with aromatic sulphoxides such as dibenzyl, diphenyl and di-4-chlorophenyl sulphoxides have been studied at various pH values and the spectral and kinetic properties of the transients determined. e(aq)- addition to dibenzyl sulphoxide was found to lead to the scission of the C-S bond giving benzyl radicals, but such bond breakage was not observed in other cases.

引用

页码：141 / 147

页数：7

共 8 条

[1]

FIELDEN EM, 1984, STUDY FAST PROCESSES, P49

[2]

GUHA SN, 1987, P INDIAN AS-CHEM SCI, V99, P261

[3] RADICAL CATIONS FROM ONE-ELECTRON OXIDATION OF ALIPHATIC SULFOXIDES IN AQUEOUS-SOLUTION - A RADIATION CHEMICAL STUDY [J].