SOLVENT REORGANIZATION ENERGETICS AND DYNAMICS IN CHARGE-TRANSFER PROCESSES OF TRANSITION-METAL COMPLEXES

被引：0

作者：

ZHANG, X ^{[1
]}

KOZIK, M ^{[1
]}

SUTIN, N ^{[1
]}

WINKLER, JR ^{[1
]}

机构：

[1] BROOKHAVEN NATL LAB, DEPT CHEM, UPTON, NY 11973 USA

来源：

ADVANCES IN CHEMISTRY SERIES | 1991年 / 228期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Time-resolved and steady-state luminescence measurements were used to probe the energetics and dynamics of solvation in two different transition metal complexes. The metal-to-ligand charge-transfer excited state of Ru(bpy)2(CN)2 (bpy is bipyridine) was studied in a series of alphatic alcohols, and the luminescent excited state of Mo2Cl4[P(CH3)3]4 was studied in aprotic organic solvents. The energetics of excited-state solvation were evaluated from the shapes and positions of the steady-state luminescence spectra recorded at low (approximately 10 K) and room temperatures. The dynamics of excited-state solvation were probed by time-resolved emission spectroscopy.

引用

页码：247 / 264

页数：18

共 50 条

[21] CHARGE-TRANSFER INTERACTIONS BETWEEN TRANSITION-METAL HEXAFLUORIDES AND XENON [J].

WEBB, JD ;

BERNSTEIN, ER .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (02) :483-485

[22] CHARGE-TRANSFER STATES OF TRANSITION-METAL AND RARE-EARTH IONS - THEIR ROLE IN RECOMBINATION PROCESSES [J].

GODLEWSKI, M .

ACTA PHYSICA POLONICA A, 1993, 84 (05) :849-855

[23] PICOSECOND DYNAMICS OF SOLVENT TRAPPING FOLLOWING ELECTRON-TRANSFER IN TRANSITION-METAL COMPLEXES [J].

YABE, T ;

ANDERSON, DR ;

ORMAN, LK ;

CHANG, YJ ;

HOPKINS, JB .

JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (06) :2302-2306

[24] IONIC PHOTODISSOCIATION OF CHARGE-TRANSFER COMPLEXES - SOLUTE-SOLVENT CHARGE-TRANSFER COMPLEXES [J].

KIMURA, K ;

ACHIBA, Y .

JOURNAL OF PHOTOCHEMISTRY, 1976, 5 (02) :188-189

[25] EFFECTS OF SOLVENT ON CHARGE-TRANSFER COMPLEXES [J].

MOUCHET, JP ;

ROUSSET, Y .

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE, 1980, 77 (06) :529-536

[26] SOLVENT EFFECTS OF CHARGE-TRANSFER COMPLEXES [J].

AIHARA, JI ;

TSUDA, M ;

INOKUCHI, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1969, 42 (07) :1824-+

[27] Solvent effects on the energetics of intermolecular charge-transfer reactions [J].

1600, (112)

[28] SOLVENT EFFECTS ON THE ENERGETICS OF INTERMOLECULAR CHARGE-TRANSFER REACTIONS [J].

ODRISCOLL, E ;

SIMON, JD ;

PETERS, KS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (20) :7091-7098

[29] MOLECULAR-ORBITAL CALCULATIONS ON TRANSITION-METAL COMPLEXES, CHARGE-TRANSFER SPECTRA AND SEQUENCE OF METAL AND LIGAND ORBITALS [J].

VANDERLUGT, WT .

INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 1972, 6 (05) :859-+

[30] Femtosecond absorption spectroscopy of transition metal charge-transfer complexes [J].

McCusker, JK .

ACCOUNTS OF CHEMICAL RESEARCH, 2003, 36 (12) :876-887

← 1 2 3 4 5 →