MEDIUM BASICITY EFFECTS ON TRANSITION-STATE STRUCTURE OF E2 REACTIONS - KINETIC STUDY OF REACTION OF 1-CHLORO-1-PHENYL-2-ARYLETHANES WITH CROWN ETHER COMPLEXED POTASSIUM TERT-BUTOXIDE IN TERT-BUTYL ALCOHOL

被引：9

作者：

ALUNNI, S ^{[1
]}

BACIOCCHI, E ^{[1
]}

PERUCCI, P ^{[1
]}

机构：

[1] UNIV PERUGIA,DEPT CHIM,I-06100 PERUGIA,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1977年 / 42卷 / 12期

关键词：

D O I：

10.1021/jo00432a035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

引用

页码：2170 / 2172

页数：3

共 10 条

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[2] ELIMINATION-REACTIONS OF 1,2-DIARYL-1-CHLOROETHANES PROMOTED BY SODIUM ETHOXIDE IN ETHANOL - KINETIC EFFECTS OF ALPHA-PHENYL AND BETA-PHENYL SUBSTITUENTS [J].

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[3]

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[5] MECHANISMS OF ELIMINATION REACTIONS .8. EFFECT OF ADDED DIMETHYL SULFOXIDE ON RATES ISOTOPE EFFECTS AND SUBSTITUENT EFFECTS IN REACTION OF 2-ARYLETHYL BROMIDES WITH POTASSIUM T-BUTOXIDE IN T-BUTYL ALCOHOL [J].

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[6]

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[7]

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[8] ISOTOPE-EFFECT STUDIES ON ELIMINATION-REACTIONS .11. NATURE OF TRANSITION-STATE FOR E2 REACTION OF 2-PHENYLETHYLDIMETHYLANILINIUM SALTS CONTAINING SUBSTITUENTS IN ANILINE RING WITH SODIUM ETHOXIDE IN ETHANOL [J].

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CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (23) :3513-3525

[9] A SIMPLE THEORY FOR PREDICTING EFFECTS OF SUBSTITUENT CHANGES ON TRANSITION-STATE GEOMETRY [J].

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[10] ELIMINATION MECHANISM - DEUTEROXIDE-HYDROXIDE ISOTOPE-EFFECTS AS A MEASURE OF PROTON-TRANSFER IN TRANSITION-STATES FOR E2 ELIMINATION OF 2-(P-TRIMETHYLAMMONIOPHENYL)ETHYL ONIUM IONS AND HALIDES - MAPPING OF REACTION-COORDINATE MOTION [J].

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