ON THE REACTIVITY OF SILAETHENE ME2SI=C(SIME3)2 - STEREOSPECIFICITY OF DIELS-ALDER REACTIONS WITH HEXADIENES

被引：11

作者：

WIBERG, N

FISCHER, G

WAGNER, S

机构：

[1] Institut Für Anorganische Chemie, Universität München, München, D-8000

来源：

CHEMISCHE BERICHTE | 1991年 / 124卷 / 04期

关键词：

SILAETHENE; DIELS-ALDER REACTION;

D O I：

10.1002/cber.19911240416

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[4 + 2] Cycloaddition of trans,trans- and cis,trans-2,4-hexadiene to silaethene Me2Si = C(SiMe3)2 (1) takes place stereo-specifically in one step with formation of 3 and 4, respectively. In addition, both reactions lead to ene products 5, 6.

引用

页码：769 / 771

页数：3

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