THE TEMPERATURE AND DENSITY DEPENDENCES OF THE SELF-DIFFUSION COEFFICIENT AND THE SHEAR VISCOSITY OF LIQUID TRICHLOROMETHANE

被引:37
|
作者
HARRIS, KR [1 ]
LAM, HN [1 ]
RAEDT, E [1 ]
EASTEAL, AJ [1 ]
PRICE, WE [1 ]
WOOLF, LA [1 ]
机构
[1] AUSTRALIAN NATL UNIV,RES SCH PHYS SCI,ATOM & MOLEC PHYS LABS,CANBERRA,ACT 2601,AUSTRALIA
关键词
D O I
10.1080/00268979000102441
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Self-diffusion coefficients for trichloromethane are reported for the temperature range 5-75-degrees-C at pressures up to 400 MPa, having been measured by both diaphragm cell and NMR spin-echo techniques. Shear viscosities, determined with a falling-body viscometer, are reported in the range 5-50-degrees-C and up to 300 MPa. The results are analysed with the aid of models derived from computer simulation molecular dynamics data.
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页码:1205 / 1221
页数:17
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