HIGH-ACTIVITY OF COPPER-BORALITE IN THE REDUCTION OF NITRIC-OXIDE WITH PROPANE OXYGEN

被引:16
作者
CENTI, G
PERATHONER, S
DALLOLIO, L
机构
[1] Dip. Chimica Industriale e dei Materiali, 40136 Bologna
关键词
COPPER-BORALITE; NITRIC OXIDE REDUCTION; PROPANE;
D O I
10.1016/0926-3373(94)00040-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The activity of ZSM-5 and boralite zeolites (Na, H and Cu forms) in the reduction of nitric oxide with propane/oxygen is compared. Copper ion-exchanged boralite is more active than a corresponding Cu-ZSM-5 sample with the same MFI structure, Si/M (M = Al or B) ratio and copper content, showing that in copper-exchanged samples Bronsted acid sites do not play a key role in the reaction mechanism, in contrast to that found for samples without the exchanged transition metal.
引用
收藏
页码:L275 / L281
页数:7
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