THE ADHESION OF ELASTOMER-COATED GLASS-FIBERS TO AN EPOXY MATRIX .1. THE EFFECT OF THE SURFACE TREATMENTS ON THE TENSILE-STRENGTH OF THE GLASS-FIBERS

E-glass fibers were subjected to various surface treatments to study the interfacial adhesion with an epoxy matrix by means of the fragmentation test. The glass fibers considered were both untreated and treated with gamma-aminopropyltriethoxysilane (gamma-APS). In addition, glass fibers were coated with a thin layer of a crosslinkable elastomer including (or not) a silane coupling agent. To evaluate the effect of the coating process, the glass fibers were also passed through the pure solvent (washed fibers). The tensile strength of glass fibers at short length (near the critical length, I-c, for the fragmentation test) cannot be measured directly, thus, extrapolation techniques were used. The Weibull statistics technique was applied and accurately described the tensile strength data of the tensile strength at various fiber gauge lengths for the different surface treatments. Nevertheless, the Weibull parameter, m, changes with the gauge length, and therefore, the extrapolation value at I-c depends on the method. The tensile strength of the silane-treated glass fibers is higher than for the untreated fibers, in agreement with reported data. This effect could be attributed to the protection against water provided by the silane sizing. The coating process does not induce any damage of the glass fibers since the washed fibers display mechanical properties close to those obtained for the untreated fibers. An additional effect is observed for the elastomer-coated fibers which present the highest tensile strength. This effect could be attributed to an improved protection and/or elimination of the weakest filaments in the glass strand during the treatment.