SYNTHESIS OF ENANTIOMERICALLY ENRICHED TRICARBONYL(VINYLKETENE)IRON(O) COMPLEXES

被引:5
作者
BENYUNES, SA [1 ]
GIBSON, SE [1 ]
WARD, MF [1 ]
机构
[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND
关键词
D O I
10.1016/0957-4166(95)00329-N
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Addition of tricarbonyl(vinylketene)iron(0) complexes 2a-d to 0.5 equiv. of a phosphoramidate anion derived from (S)-alpha-methylbenzylamine affords the first enantiomerically enriched samples of 2a-d; the absolute configurations of 2a-d have been established as 5pS.
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页码:2517 / 2520
页数:4
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