A NEW FAMILY OF CHIRAL BINAPHTHYL-DERIVED CYCLOPHANE RECEPTORS - COMPLEXATION OF PYRANOSIDES

被引：175

作者：

ANDERSON, S

NEIDLEIN, U

GRAMLICH, V

DIEDERICH, F

机构：

[1] ETH ZENTRUM,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND

[2] ETH ZENTRUM,INST KRISTALLOG & PETROG,ZURICH,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 15期

关键词：

BIARYLS; CARBOHYDRATES; CYCLOPHANES; HYDROGEN BONDING; MOLECULAR RECOGNITION;

D O I：

10.1002/anie.199515961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Even in the presence of a protic solvent (up to 20% v/v CD3OD) the optically active cyclophane tetraanion in (R,R,R,R)‐1 binds to carbohydrates such as 1‐O‐octyl‐β‐D‐glycopyranoside. In addition, neutral cyclophanes with similarly highly organized cavities are suitable binders in chloroform. The macrocycles are synthesized by Glaser–Hay coupling of novel chiral diethynylated 1,1'‐binaphthyl monomers. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1596 / 1600

页数：5

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