MODEL STUDIES DIRECTED TOWARDS MICROALGA POLYETHER TOXINS - A STEREOSELECTIVE ENTRY INTO C10 CIS-FUSED AND TRANS-FUSED OXANE-OXEPANE SUBUNITS

被引：16

作者：

ALVAREZ, E ^{[1
]}

ZURITA, D ^{[1
]}

MARTIN, JD ^{[1
]}

机构：

[1] UNIV LA LAGUNA,CSIC,CTR PROD NAT ORGAN ANTONIO GONZALEZ,CTRA LA ESPERANZA 2,E-38206 LA LAGUNA,SPAIN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 20期

关键词：

D O I：

10.1016/S0040-4039(00)79692-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new synthetic process for the construction of cis- and transfused oxane-oxepane systems starting from (z,z)-cyclodeca-2,7-dien-1-ol is described. The Ti(O(i)Pr)4-catalysed transannular oxirane ring expansion is invoked to explain the chemoselective formation of the 11-oxobicyclo [4.4.1] undecane intermediate.

引用

页码：2245 / 2248

页数：4

共 14 条

[11] ACTIVATION OF 7-ENDO OVER 6-EXO EPOXIDE OPENINGS - SYNTHESIS OF OXEPANE AND TETRAHYDROPYRAN SYSTEMS [J].