A NEW DETERMINATION OF THE BINARY PHASE-DIAGRAM OF H2-HE MIXTURES AT 296-K

被引:23
作者
LOUBEYRE, P
LETOULLEC, R
PINCEAUX, JP
机构
[1] Lab. de Phys. des Milieux Condenses, Paris VI Univ.
关键词
D O I
10.1088/0953-8984/3/18/012
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
The properties of dense H-2-He mixtures have been measured in a diamond anvil cell (DAC) at T = 296 K by direct visualization and Raman spectroscopy. The discrepancies that existed between the two previous high-pressure works have been resolved; they stemmed from an underestimation of the homogenization time of the mixture which is prepared for loading the DAC. The Raman spectroscopy measurements confirm the existence of a cusp on the fluid-fluid coexistence curve. The miscibility of one component in the solid of the other has also been investigated.
引用
收藏
页码:3183 / 3192
页数:10
相关论文
共 17 条
[1]  
CHARON L, 1990, UNPUB 28TH P EHPRG C
[2]  
HIRSCHFELDER JO, 1964, MOL THEORY GASES LIQ, pCH8
[3]  
HUBBARD WB, 1989, SIMPLE MOL SYSTEMS V
[4]   DIAMOND ANVIL CELL AND HIGH-PRESSURE PHYSICAL INVESTIGATIONS [J].
JAYARAMAN, A .
REVIEWS OF MODERN PHYSICS, 1983, 55 (01) :65-108
[5]  
LETOULLEC R, 1908, HIGH PRESS RES, V1, P77
[6]   BINARY PHASE-DIAGRAMS OF H-2-HE MIXTURES AT HIGH-TEMPERATURE AND HIGH-PRESSURE [J].
LOUBEYRE, P ;
LETOULLEC, R ;
PINCEAUX, JP .
PHYSICAL REVIEW B, 1987, 36 (07) :3723-3730
[7]   HELIUM COMPRESSIONAL EFFECT ON H2 MOLECULES SURROUNDED BY DENSE H2-HE MIXTURES [J].
LOUBEYRE, P ;
LETOULLEC, R ;
PINCEAUX, JP .
PHYSICAL REVIEW B, 1985, 32 (11) :7611-7613
[8]  
LOUBEYRE P, UNPUB
[9]  
MAO HK, 1989, SCIENCE, V244, P1462, DOI 10.1126/science.244.4911.1462
[10]   SOLUBILITY OF H2-HE MIXTURES IN FLUID PHASES TO 1 GPA [J].
REE, FH .
JOURNAL OF PHYSICAL CHEMISTRY, 1983, 87 (15) :2846-2852