LIGAND-EXCHANGE REACTIONS OF BIS(ACETYLACETONATO)DIOXO-MOLYBDENNM(VI) - CRYSTAL-STRUCTURES OF [SALICYLALDEHYDE-BENZOYLHYDRAZONATO(2-)]DIOXO-METHANOL-MOLYBDENUM(VI) AND [BENZOYLACETONE-BENZOYLHYDRAZONATO(2-)]DIOXO-TRIPHENYLPHOSPHANEOXIDE-MOLYBDENUM(VI)

被引：27
作者：
BANSSE, W
LUDWIG, E
SCHILDE, U
UHLEMANN, E
WELLER, F
LEHMANN, A
机构：
[1] UNIV POTSDAM,INST ANORGAN CHEM & DIDAKT CHEM,D-14415 POTSDAM,GERMANY
[2] UNIV MARBURG,FACHBEREICH CHEM,W-3550 MARBURG,GERMANY
[3] BUNDESANSTALT MAT FORSCHUNG & PRUFUNG,BERLIN,GERMANY
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 07期
关键词：
DIOXOMOLYBDENUM(VI) COMPLEXES; CRYSTAL STRUCTURES;
D O I：
10.1002/zaac.19956210730
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The products of ligand exchange reactions between bis(acetylacetonato)dioxo-molybdenum(VI) and tridentate diacidic ligands H(2)L in the presence of triphenylphosphane were found by mass spectrometry to be complexes of the type MoO(2)L. In the case of salicylaldehyde 2-hydroxyanil MoL(2) could also be identified. The compounds MoO(2)L were crystallized as complexes with methanol or triphenylphosphane oxide. Crystallographic data see ''Inhaltsubersicht''.
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页码：1275 / 1281
页数：7
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