NEW SYNTHESIS OF ALIPHATIC ISOTHIOCYANATES FROM PRIMARY AMINES, CONVENIENT FOR IN-SITU USE

被引：31

作者：

BOAS, U ^{[1
]}

JAKOBSEN, MH ^{[1
]}

机构：

[1] UNIV COPENHAGEN,DEPT GEN & ORGAN CHEM,CTR MED BIOTECHNOL,HC ORSTED INST,DK-2100 COPENHAGEN,DENMARK

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.

引用

页码：1995 / 1996

页数：2

共 50 条

[31] A NEW METHOD FOR REDUCTIVE DEAMINATION OF PRIMARY ALIPHATIC-AMINES [J].

WIRTH, T ;

RUCHARDT, C .

CHIMIA, 1988, 42 (06) :230-231

[32] Use of PyBOP as a convenient activator for the synthesis of nitriles from primary amides [J].

Bose, DS ;

Narsaiah, AV .

SYNTHESIS-STUTTGART, 2001, (03) :373-375

[33] A CONVENIENT METHOD FOR THE SYNTHESIS OF 2-OXAZOLIDINONES FROM ETHYLENE CARBONATE AND PRIMARY ARYL AMINES [J].

Gong, Hang ;

Yang, Nian-fa .

HETEROCYCLES, 2009, 78 (08) :2093-2100

[34] The synthesis of alkyl carbamates from primary aliphatic amines and dialkyl carbonates in supercritical carbon dioxide [J].

Selva, M ;

Tundo, P ;

Perosa, A .

TETRAHEDRON LETTERS, 2002, 43 (07) :1217-1219

[35] A convenient synthesis of trifluoroacetamides from sodium trifluoroacetate and amines [J].

Zhou, QZ ;

Chen, ZC .

SYNTHETIC COMMUNICATIONS, 2000, 30 (17) :3189-3194

[36] SYNTHESIS OF ALIPHATIC TERTIARY AMINES FROM THIOPHENE DERIVATIVES [J].

GOLDFARB, JL ;

IBRAGUIMOVA, MB .

DOKLADY AKADEMII NAUK SSSR, 1956, 106 (03) :469-472

[37] NEW APPROACH TO SYNTHESIS OF PRIMARY AMINES, ISOTHIOCYANATES, AND 1-AMINOALKANEPHOSPHONATES VIA N-PHOSPHINYL ALDOXIMES AND KETOXIMES [J].

KRZYZANOWSKA, B ;

STEC, WJ .

SYNTHESIS-STUTTGART, 1978, (07) :521-524

[38] A NEW METHOD FOR SYNTHESIS OF PRIMARY AMINES [J].

STETTER, H ;

THEISEN, D .

CHEMISCHE BERICHTE-RECUEIL, 1969, 102 (05) :1641-&

[39] A NEW SYNTHESIS OF SECONDARY ALLYLIC ALIPHATIC AND AROMATIC-AMINES [J].

SPALTENSTEIN, A ;

CARPINO, PA ;

HOPKINS, PB .

TETRAHEDRON LETTERS, 1986, 27 (02) :147-150

[40] MERCURATION DEMERCURATION OF ALIPHATIC ISOCYANATES - A NEW MILD ROUTE TO PRIMARY AMINES [J].

MALANGA, C ;

URSO, A ;

LARDICCI, L .

TETRAHEDRON LETTERS, 1995, 36 (48) :8859-8860

← 1 2 3 4 5 →