NEW SYNTHESIS OF ALIPHATIC ISOTHIOCYANATES FROM PRIMARY AMINES, CONVENIENT FOR IN-SITU USE

被引：31

作者：

BOAS, U ^{[1
]}

JAKOBSEN, MH ^{[1
]}

机构：

[1] UNIV COPENHAGEN,DEPT GEN & ORGAN CHEM,CTR MED BIOTECHNOL,HC ORSTED INST,DK-2100 COPENHAGEN,DENMARK

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001995

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Primary aliphatic amines react with carbon disulfide in the presence of BOP (benzotriazole-1-yl-oxy-tris(dimethylamino)phosphonium hexafluorophosphate 1, giving the corresponding isothiocyanates in good to high yields and high purity; a number of isothiocyanates are synthesized and isolated or generated in situ and treated with a nucleophile.

引用

页码：1995 / 1996

页数：2

共 50 条

[1] A CONVENIENT SYNTHESIS OF ISOTHIOCYANATES FROM PRIMARY NITROALKANES [J].

KIM, JN ;

SONG, JH ;

RYU, EK .

SYNTHETIC COMMUNICATIONS, 1994, 24 (08) :1101-1105

[2] A NEW SYNTHESIS OF ALIPHATIC ISOTHIOCYANATES [J].

JOCHIMS, JC ;

SEELIGER, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (02) :174-&

[3] A CONVENIENT PROCEDURE FOR SYNTHESIZING THE PRIMARY ALIPHATIC-AMINES [J].

GANIN, EV ;

ANIKIN, VF ;

KAMALOV, GL .

UKRAINSKII KHIMICHESKII ZHURNAL, 1983, 49 (12) :1311-1312

[4] CONVENIENT IMPROVED SYNTHESES OF ISOCYANATES OR ISOTHIOCYANATES FROM AMINES [J].

MOLINA, P ;

ALAJARIN, M ;

ARQUES, A .

SYNTHESIS-STUTTGART, 1982, (07) :596-597

[5] THE SYNTHESIS OF ISOTHIOCYANATES FROM AMINES [J].

HODGKINS, JE ;

ETTLINGER, MG .

JOURNAL OF ORGANIC CHEMISTRY, 1956, 21 (04) :404-405

[6] The use of bis(aminol) ethers derived from aliphatic primary amines in the synthesis of secondary and tertiary amines [J].

Heaney, H ;

Papageorgiou, G .

TETRAHEDRON, 1996, 52 (10) :3473-3486

[7] Convenient synthesis of protected primary amines from nitriles [J].

Caddick, S ;

Haynes, AKD ;

Judd, DB ;

Williams, MRV .

TETRAHEDRON LETTERS, 2000, 41 (18) :3513-3516

[8] CONVENIENT SYNTHESIS OF ISOTHIOCYANATES FROM DITHIOCARBAMATES [J].

FUJITA, H ;

ENDO, R ;

MURAYAMA, K .

CHEMISTRY LETTERS, 1973, (08) :883-886

[9] A CONVENIENT AND VERSATILE SYNTHESIS OF CHIRAL ALIPHATIC AND ALLYLIC AMINES [J].

SAARI, WS ;

FISHER, TE .

SYNTHESIS-STUTTGART, 1990, (06) :453-454

[10] A convenient method for the synthesis of poly(β-hydroxyiminoalkyl)amines from aliphatic nitro compounds [J].

Semakin, Artem N. ;

Sukhorukov, Alexey Yu. ;

Lesiv, Alexey V. ;

Khomutova, Yulia A. ;

Ioffe, Sema L. ;

Lyssenko, Konstantin A. .

SYNTHESIS-STUTTGART, 2007, (18) :2862-2866

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