Bis(dimethyl sulfoxide-kappa O)tetrakis(mu(2)-3,4,5-trimethoxybenzoato-kappa O-2:O ')dizinc

被引：0

作者：

Deutsch, Diana ^{[1
]}

Zevaco, Thomas ^{[1
]}

Walter, Olaf ^{[1
]}

机构：

[1] IKFT, Hermann Von Helmholtz Pl 1,KIT Campus Nord, D-76344 Leopoldshafen, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

D O I：

10.1107/S1600536813023118

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The colourless title complex, [Zn-2(C10H11O5)(4)(C2H6OS)(2)],crystallizes with one half-molecule in the asymmetric unit, the other half of the molecule being generated by a crystallographic inversion center. The structure shows a mu(2)-O:O ' bridging mode of the four 3,4,5-trimethoxybenzoate ligands finally stabilizing the two Zn-II atoms in the dinuclear complex in a distorted square-pyramidal environment. The fifth coordination site in the apical position of the pyramid is occupied by a coordinating dimethyl sulfoxide solvent molecule equally disordered over two positions.

引用

页码：M519 / +

页数：9

共 10 条

[1]

Bruker, 1997, SMART SAINT SADABS

[2] WinGX and ORTEP for Windows: an update [J].

Farrugia, Louis J. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2012, 45 :849-854

[3] Novel luminescent metal-organic frameworks [Eu2L3(DMSO)2(MeOH)2]•2DMSO•3H2O and [Zn2L2(DMSO)2]•1.6H2O (L=4,4′-ethyne-1,2-diyldibenzoate) [J].

Pham, Bich Tram Nguyen ;

Lund, Liisa M. ;

Song, Datong .

INORGANIC CHEMISTRY, 2008, 47 (14) :6329-6335

[4] Zinc Paddlewheel Dimers Containing a Strong π•••π Stacking Supramolecular Synthon: Designed Single-Crystal to Single-Crystal Phase Changes and Gas/Solid Guest Exchange [J].

Reger, Daniel L. ;

Debreczeni, Agota ;

Smith, Mark D. .

INORGANIC CHEMISTRY, 2011, 50 (22) :11754-11764

[5] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[6] Assembly of a microporous metal-organic framework [Zn(bpdc)(DMSO)] (bpdc=4,4′-biphenyldicarboxylate) based on paddle-wheel units affording guest inclusion [J].

Tao, J ;

Yin, X ;

Huang, RB ;

Zheng, LS ;

Ng, SW .

INORGANIC CHEMISTRY COMMUNICATIONS, 2002, 5 (11) :975-977

[7] publCIF: software for editing, validating and formatting crystallographic information files [J].

Westrip, Simon P. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925

[8] Poly[[bis[(dimethyl sulfoxide) zinc(II)]-di-μ4-benzene-1,4-dicarboxylato] dimethyl sulfoxide pentasolvate] [J].

Yang, SY ;

Long, LS ;

Huang, RB ;

Zheng, LS ;

Ng, SW .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M1671-M1673

[9] An easy way to achieve three-dimensional metal-organic coordination polymers:: synthesis and crystal structure of dizinc diisophthalate bis-dimethylsulfoxide monohydrate:: [Zn2(ip)4(DMSO)2(H2O)•3DMSO]n [J].

Zevaco, Thomas A. ;

Maennle, Daniel ;

Walter, Olag ;

Dinjus, Eckhard .

APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (11) :970-977

[10]

ZSOLNAI L, 1996, XPMA

← 1 →