THE STEP-GROWTH POLYMERIZATION OF DITHIOLS AND DIISOCYANATES .1. DSC AND SPECTROSCOPIC INVESTIGATIONS REGARDING THE MECHANISM

被引:3
作者
FLAMMERSHEIM, HJ [1 ]
ECKARDT, N [1 ]
OPFERMANN, J [1 ]
机构
[1] NETZSCH GERATEBAU GMBH SELB,D-95100 SELB,GERMANY
关键词
D O I
10.1016/0040-6031(93)80335-8
中图分类号
O414.1 [热力学];
学科分类号
摘要
The polyaddition reaction of diisocyanates and dithiols was investigated by isothermal DSC measurements and by the spectroscopic methods IRS, UVS and NMR. Using multivariate, non-linear regression, a reaction mechanism is suggested, which is capable of explaining all the experimental results.
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页码:281 / 287
页数:7
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