USE OF ALTERNATIVE REACTION MEDIA FOR AN ENVIRONMENTALLY SAFER CHEMICAL PRODUCTION

被引:1
作者
ZLOKARNIK, M
机构
[1] Bayer AG, Leverkusen
关键词
D O I
10.1002/cite.330631006
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The way in which a chemical reaction is carried out and the composition of the reaction mixture dictate the degree of difficulty of downstream processing operations, not only in terms of energy consumption but also with respect to environmental pollution. A specific environmental protection that is an integral part of the production process must therefore begin with the examination of the chemical rection step. Restructuring a process from a reaction engineering point of view includes two important aspects of which the technical implementation has not yet been systematically examined and which therefore should promise a significant potential for innovation. These are the integration of modern separation operations in the chemical reactor with the aim of shifting the chemical equilibrium and the choice of an alternative reaction medium; although the latter also serves the same purpose, it can bring about a significant reduction in environmental pollution. This aspect is the focus of this paper, in which the advantages of molten salts, supercritical fluids and microemulsions as alternative reaction media are discussed.
引用
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页码:994 / 999
页数:6
相关论文
共 33 条
[1]  
[Anonymous], 1990, PRODUKTIONSINTEGRIER
[2]   VALUE RECOVERY FROM PLASTICS WASTE BY PYROLYSIS IN MOLTEN-SALTS [J].
BERTOLINI, GE ;
FONTAINE, J .
CONSERVATION & RECYCLING, 1987, 10 (04) :331-343
[3]  
Blander M., 1964, MOLTEN SALT CHEM
[4]  
BRAUNSTEIN J, 1973, ADV MOLTEN SALT CHEM, V1
[5]  
Dehmlow E. V., 1983, PHASE TRANSFER CATAL
[6]   INDUSTRIAL APPLICATIONS OF PHASE-TRANSFER CATALYSIS (PTC) - PAST, PRESENT AND FUTURE [J].
FREEDMAN, HH .
PURE AND APPLIED CHEMISTRY, 1986, 58 (06) :857-868
[7]  
GORDON JE, 1969, TECHNIQUES METHODS O, V1, P51
[8]  
HATT BW, 1982, MOLTEN SALT TECHNOLO, P395
[9]  
JOHNSTON KP, 1988, SUPERCRITICAL FLUIDS, V2, P907
[10]   HOW TO STUDY MICROEMULSIONS [J].
KAHLWEIT, M ;
STREY, R ;
HAASE, D ;
KUNIEDA, H ;
SCHMELING, T ;
FAULHABER, B ;
BORKOVEC, M ;
EICKE, HF ;
BUSSE, G ;
EGGERS, F ;
FUNCK, T ;
RICHMANN, H ;
MAGID, L ;
SODERMAN, O ;
STILBS, P ;
WINKLER, J ;
DITTRICH, A ;
JAHN, W .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1987, 118 (02) :436-453