PROPERTIES OF A NEW PEROVSKITE OXIDE SR2VO4

被引：79
作者：
CYROT, M
LAMBERTANDRON, B
SOUBEYROUX, JL
REY, MJ
DEHAUHT, P
CYROTLACKMANN, F
FOURCAUDOT, G
BEILLE, J
THOLENCE, JL
机构：
[1] LAB CRISTALLOG GRENOBLE,F-38000 GRENOBLE,FRANCE
[2] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE
[3] CEN GRENOBLE,F-38042 GRENOBLE,FRANCE
[4] LAB ETUD PROPRIETES ELECT SOLIDES,F-38000 GRENOBLE,FRANCE
[5] CTR RECH TRES BASSES TEMP,F-38000 GRENOBLE,FRANCE
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1990年 / 85卷 / 02期
关键词：
D O I：
10.1016/S0022-4596(05)80090-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We have synthesized a new perovskite of the K2NiF4 structure Sr2VO4. The formal valence of vanadium is 4+. We have performed X-ray and neutron experiments which show that the octahedra surrounding the vanadium is elongated. The compound is insulating and antiferromagnetic. These properties are reminiscent of those of La2CuO4 which becomes a high Tc superconductor when doped, the copper d9 ion being replaced by the vanadium d1 ion. © 1990 Academic Press, Inc.
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页码：321 / 325
页数：5
相关论文
共 15 条
[1]   THE RESONATING VALENCE BOND STATE IN LA2CUO4 AND SUPERCONDUCTIVITY [J].
ANDERSON, PW .
SCIENCE, 1987, 235 (4793) :1196-1198
[2]   POSSIBLE HIGH-TC SUPERCONDUCTIVITY IN THE BA-LA-CU-O SYSTEM [J].
BEDNORZ, JG ;
MULLER, KA .
ZEITSCHRIFT FUR PHYSIK B-CONDENSED MATTER, 1986, 64 (02) :189-193
[3]   MAGNETIC-PROPERTIES OF QUASI-2-DIMENSIONAL LA2NIO4 [J].
BUTTREY, DJ ;
HONIG, JM ;
RAO, CNR .
JOURNAL OF SOLID STATE CHEMISTRY, 1986, 64 (03) :287-295
[4]   ALKALINE-EARTH VANADIUM (IV) OXIDES HAVING AVO3 COMPOSITION [J].
CHAMBERL.BL ;
DANIELSO.PS .
JOURNAL OF SOLID STATE CHEMISTRY, 1971, 3 (02) :243-&
[5]   ARE HIGH-TC SUPERCONDUCTORS DOPED MOTT INSULATORS [J].
CYROT, M .
SOLID STATE COMMUNICATIONS, 1987, 63 (11) :1015-1018
[6]  
CYROT M, 1987, SOLID STATE COMMUN, V62, P82
[7]   STUDY OF MAGNETIC, ELECTRICAL AND OPTICAL-PROPERTIES OF PHASES OF PEROVSKITE STRUCTURE SRVO2.90 AND SRVO3 [J].
DOUGIER, P ;
FAN, JCC ;
GOODENOUGH, JB .
JOURNAL OF SOLID STATE CHEMISTRY, 1975, 14 (03) :247-259
[8]   CRYSTAL-CHEMISTRY AND MAGNETIC-PROPERTIES OF LAYERED METAL-OXIDES POSSESSING THE K2NIF4 OR RELATED STRUCTURES [J].
GANGULY, P ;
RAO, CNR .
JOURNAL OF SOLID STATE CHEMISTRY, 1984, 53 (02) :193-216
[9]  
KASIMOV GG, 1974, ZH NEORG KHIM+, V19, P148
[10]   NONSTOICHIOMETRY AND ELECTRICAL-CONDUCTIVITY OF STRONTIUM NIOBATES WITH PEROVSKITE STRUCTURE .1. DEFECT STRUCTURE OF SR(SR1/3NB2/3)O3 [J].
LECOMTE, J ;
LOUP, JP ;
HERVIEU, M ;
RAVEAU, B .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1981, 65 (02) :743-752
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