ASYMMETRIC CATALYSTS .55. OPTICALLY-ACTIVE DELTACYCLANES AND DELTACYCLENES BY ENANTIOSELECTIVE CATALYSIS

被引：39

作者：

BRUNNER, H

MUSCHIOL, M

PRESTER, F

机构：

[1] Institut Für Anorganische Chemie, Universität Regensburg, Regensburg, D-8400

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 06期

关键词：

D O I：

10.1002/anie.199006521

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of norbornadiene with phenylacetylene leading to the deltacycles 1 can be controlled enantioselectively with norphos/cobalt catalysts. An optical yield of 98.4 % ee with complete conversion is achieved. The reaction thus ranks as one of the best enantioselective reactions catalyzed by transition metal complexes that have been reported so far. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：652 / 653

页数：2

相关论文

共 10 条

[1] ASYMMETRIC HYDROGENATION OF (Z)-ALPHA-(ACETYLAMINO)-CINNAMIC ACID BY A RH-NORPHOS CATALYST [J].

BRUNNER, H ;

PIERONCZYK, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1979, 18 (08) :620-621

[2] ASYMMETRIC CATALYZES .5. ENANTIOSELECTIVE AMINO-ACID SYNTHESIS BY HYDROGENATION OF PROCHIRAL OLEFINS WITH RH-COMPLEXES OF THE NEW OPTICALLY-ACTIVE CHELATING PHOSPHANE NORPHOS [J].

BRUNNER, H ;

PIERONCZYK, W ;

SCHONHAMMER, B ;

STRENG, K ;

BERNAL, I ;

KORP, J .

CHEMISCHE BERICHTE-RECUEIL, 1981, 114 (03) :1137-1149

[3]

Brunner H., 1979, ANGEW CHEM, V91, P655

[4]

BRUNNER H, IN PRESS MONATSH CHE

[5] DIAZADIENES AS CONTROLLING LIGANDS IN HOMOGENEOUS CATALYSIS .16. GAS-CHROMATOGRAPHIC SEPARATION OF ENANTIOMERIC OLEFINS [J].

EHLERS, J ;

KONIG, WA ;

LUTZ, S ;

WENZ, G ;

DIECK, HT .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (11) :1556-1558

[6]

Ehlers J., 1988, ANGEW CHEM, V27, p[1556, 1614]

[7] ASYMMETRIC CATALYTIC REDUCTION WITH TRANSITION-METAL COMPLEXES .1. CATALYTIC SYSTEM OF RHODIUM(I) WITH (-)-2,3-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)BUTANE - NEW CHIRAL DIPHOSPHINE [J].

KAGAN, HB ;

DANG, TP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (18) :6429-&

[8] SCOPE OF THE COBALT-CATALYZED [2+2+2] HOMO-DIELS-ALDER REACTION [J].

LAUTENS, M ;

CRUDDEN, CM .

ORGANOMETALLICS, 1989, 8 (11) :2733-2735

[9]

LYONS JE, 1980, ANN NY ACAD SCI, V333, P273

[10] UBER DIE KATALYTISCHE ANLAGERUNG VON OLEFINEN UND ALKINEN AN NORBORNADIEN MIT NI0-VERBINDUNGEN UND EINEM NEUEN NI2-KOMPLEX [J].

SCHRAUZER, GN ;

GLOCKNER, P .

CHEMISCHE BERICHTE-RECUEIL, 1964, 97 (09) :2451-&