CONJUGATION LENGTH IN POLY(PARA-PHENYLENE)-TYPE POLYMERS

被引:139
作者
GRIMME, J [1 ]
KREYENSCHMIDT, M [1 ]
UCKERT, F [1 ]
MULLEN, K [1 ]
SCHERF, U [1 ]
机构
[1] MAX PLANCK INST POLYMER RES,D-55128 MAINZ,GERMANY
关键词
D O I
10.1002/adma.19950070310
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Communication: The study of well-defined, monodisperse model PPP oligomers (e.g. see Figure) has revealed that, contrary to expectations, the planarization of the re sq stem in these oligomers leads to a decrease in the effective conjugation length. This result has profound influence on the design of conducting organic materials.
引用
收藏
页码:292 / 295
页数:4
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