SYNTHESIS OF HOMOCHIRAL CYCLOPENTANE DERIVATIVES BY BECKMANN FRAGMENTATION OF 1-SUBSTITUTED 2-NORBORNANONES

被引：16

作者：

MARTINEZ, AG

VILAR, ET

FRAILE, AG

CERERO, SD

OLIVA, CD

SUBRAMANIAN, LR

MAICHLE, C

机构：

[1] UNIV COMPLUTENSE MADRID,FAC CIENCIAS,DEPT QUIM ORGAN & BIOL,E-28040 MADRID,SPAIN

[2] UNIV TUBINGEN,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 05期

关键词：

D O I：

10.1016/S0957-4166(00)86247-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The fragmentation of 2-norbornanone oximes 2 was achieved by reaction with Tf(2)O/pyridine under mild reaction conditions, yielding homochiral (or racemic) cyclopentane derivatives.

引用

页码：949 / 954

页数：6

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