CONTROL OF ION-MOLECULE REACTIONS IN THE GAS-PHASE

被引：0

作者：

GERICKE, KH

机构：

[1] Institut für Physikalische und Theoretische Chemie, Universität, Frankfurt, D-60439

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 08期

关键词：

ION-MOLECULE REACTIONS; KINETICS; PRODUCT SELECTIVITY;

D O I：

10.1002/anie.199508851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Excitation of a particular stretching vibration in the reagent ion NH 3+ influences the course of its reaction with ND3. The extent of charge transfer (a), proton transfer (b), and deuterium abstraction (c) depends on how the unbrella mode and the symmetrical breathing mode are excited. Thanks to the work of Zare et al. discussed here, the goal of controlling the reaction channels of complex molecules is a little closer. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：885 / 886

页数：2