SYNTHESIS AND REACTIONS OF A STERICALLY HINDERED OLEFIN, TRANS-2,2,3,4,5,5-HEXAMETHYL-3-HEXENE

被引：31

作者：

LENOIR, D

机构：

[1] Organisch‐Chemisches Institut, Technischen Universität München, München, D-8000

来源：

CHEMISCHE BERICHTE-RECUEIL | 1978年 / 111卷 / 01期

关键词：

D O I：

10.1002/cber.19781110140

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis and Reactions of a Sterically Hindered Olefin, trans‐2,2,3,4,5,5‐Hexamethyl‐3‐hexene Scope and limitation of the TiII‐induced coupling reaction for the sterically congested carbonyl compounds tert‐butyl methyl ketone (4), tert‐butyl ethyl ketone, and pivalaldehyde are discussed. The new olefin 5 has been prepared; the unusual chemical and physical behavior has been described by its inherent steric strain. Copyright © 1978 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

引用

页码：411 / 414

页数：4

共 15 条

[1]

BACKER HJ, 1938, REC TRAV CHIM PAYS B, V56, P967

[2]

COREY EJ, 1976, J ORG CHEM, V41, P896

[3] RELEASE OF STRAIN IN OVERCROWDED SUBSTITUTED ETHYLENES [J].