HYDROTHERMAL AND SOLID-STATE SYNTHESIS, CRYSTAL DATA AND THERMAL-STABILITY OF MONOCLINIC AND RHOMBOHEDRAL LITHIUM ZIRCONIUM-PHOSPHATE

被引：4

作者：

GOULD, WW ^{[1
]}

KOMARNENI, S ^{[1
]}

BREVAL, E ^{[1
]}

机构：

[1] PENN STATE UNIV,DEPT AGRON,UNIV PK,PA 16802

来源：

MATERIALS RESEARCH BULLETIN | 1993年 / 28卷 / 09期

关键词：

LITHIUM; ZIRCONIUM; PHOSPHATES;

D O I：

10.1016/0025-5408(93)90037-E

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

There is little or no controversy about the structure and crystal chemistry of sodium zirconium phosphate (NZP) family of materials except the Li-member. The objective of this study was to establish the structure and crystal chemistry of lithium zirconium phosphate by synthesizing it under different conditions. A lithium zirconium phosphate, LiZr2(PO4)3 has been synthesized under hydrothermal conditions at 220-degrees-C. Its unit cell is monoclinic with 'a' ranging from 15.2 to 15.4angstrom, 'b' from 8.8 to 8.9angstrom, 'c' from 8.9 to 9.2angstrom and beta from 124.8 to 125.3-degrees. This phase forms also by firing stoichiometric gels below 1080-degrees-C, above which temperature a rhombohedral form of LiZr2(PO4)3 crystallizes with hexagonal axes of a = 8.856 angstrom and c = 22.205 angstrom.

引用

页码：909 / 914

页数：6

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