HYDROTHERMAL AND SOLID-STATE SYNTHESIS, CRYSTAL DATA AND THERMAL-STABILITY OF MONOCLINIC AND RHOMBOHEDRAL LITHIUM ZIRCONIUM-PHOSPHATE

被引：4
|
作者：
GOULD, WW [1 ]
KOMARNENI, S [1 ]
BREVAL, E [1 ]
机构：
[1] PENN STATE UNIV,DEPT AGRON,UNIV PK,PA 16802
来源：
MATERIALS RESEARCH BULLETIN | 1993年 / 28卷 / 09期
关键词：
LITHIUM; ZIRCONIUM; PHOSPHATES;
D O I：
10.1016/0025-5408(93)90037-E
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
There is little or no controversy about the structure and crystal chemistry of sodium zirconium phosphate (NZP) family of materials except the Li-member. The objective of this study was to establish the structure and crystal chemistry of lithium zirconium phosphate by synthesizing it under different conditions. A lithium zirconium phosphate, LiZr2(PO4)3 has been synthesized under hydrothermal conditions at 220-degrees-C. Its unit cell is monoclinic with 'a' ranging from 15.2 to 15.4angstrom, 'b' from 8.8 to 8.9angstrom, 'c' from 8.9 to 9.2angstrom and beta from 124.8 to 125.3-degrees. This phase forms also by firing stoichiometric gels below 1080-degrees-C, above which temperature a rhombohedral form of LiZr2(PO4)3 crystallizes with hexagonal axes of a = 8.856 angstrom and c = 22.205 angstrom.
引用
收藏
页码：909 / 914
页数：6
相关论文
共 50 条
  • [1] SYNTHESIS, CRYSTAL DATA AND THERMAL-STABILITY OF MAGNESIUM ZIRCONIUM-PHOSPHATE [MGZR4(PO4)6]
    KAZAKOSKIJOWSKI, A
    KOMARNENI, S
    AGRAWAL, D
    ROY, R
    MATERIALS RESEARCH BULLETIN, 1988, 23 (08) : 1177 - 1184
  • [2] HYDROTHERMAL AND SOLID-STATE SYNTHESIS OF SODIUM ZIRCONIUM SILICOPHOSPHATES
    CLEARFIELD, A
    JERUS, P
    COTMAN, RN
    SOLID STATE IONICS, 1981, 5 (OCT) : 301 - 304
  • [3] THERMAL-STABILITY OF SUBSTITUTED PYRIDINE ADDUCTS OF BIS(ACETYLACETONATO)OXOVANADIUM(IV) IN SOLID-STATE
    SHIBUTANI, Y
    SHINRA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (05) : 1477 - 1481
  • [4] Recent development of lithium argyrodite solid-state electrolytes for solid-state batteries: Synthesis, structure, stability and dynamics
    Yu, Chuang
    Zhao, Feipeng
    Luo, Jing
    Zhang, Long
    Sun, Xueliang
    NANO ENERGY, 2021, 83
  • [5] Thermal and ionic conductivity studies of lithium aluminum germanium phosphate solid-state electrolyte
    Cui, Yuantao
    Mahmoud, Morsi M.
    Rohde, Magnus
    Ziebert, Carlos
    Seifert, Hans Juergen
    SOLID STATE IONICS, 2016, 289 : 125 - 132
  • [6] SOLID-STATE NMR ELUCIDATION OF THE ROLE OF MINERALIZERS IN THE THERMAL-STABILITY AND PHASE-TRANSFORMATIONS OF KAOLINITE
    ROCHA, J
    KLINOWSKI, J
    ADAMS, JM
    JOURNAL OF MATERIALS SCIENCE, 1991, 26 (11) : 3009 - 3018
  • [7] TRACER DIFFUSION AND THERMAL-STABILITY IN AMORPHOUS CO-ZR AND THEIR RELEVANCE FOR SOLID-STATE AMORPHIZATION
    DORNER, W
    MEHRER, H
    PHYSICAL REVIEW B, 1991, 44 (01): : 101 - 114
  • [8] SYNTHESIS, THERMAL-STABILITY, AND CRYSTAL-STRUCTURE OF ANTIMONY(V) PHOSPHATE SBOPO4
    PIFFARD, Y
    OYETOLA, S
    VERBAERE, A
    TOURNOUX, M
    JOURNAL OF SOLID STATE CHEMISTRY, 1986, 63 (01) : 81 - 85
  • [9] Synergistic effect of lithium salt and trimethyl phosphate for enhanced interface stability in solid-state lithium metal batteries
    Liu, Yali
    Hou, Wenqiang
    Zhang, Kai
    Zhang, Jintao
    Ding, Xiangdong
    Xu, Youlong
    JOURNAL OF POWER SOURCES, 2024, 592
  • [10] Hydrothermal synthesis, structure determination, and solid-state NMR study of the first organically templated scandium phosphate
    Riou, D
    Fayon, F
    Massiot, D
    CHEMISTRY OF MATERIALS, 2002, 14 (05) : 2416 - 2420
12345