ENERGETICS FOR THE DESORPTION OF HYDROXYL RADICALS FROM A PLATINUM SURFACE

被引:25
|
作者
MOONEY, CE [1 ]
ANDERSON, LC [1 ]
LUNSFORD, JH [1 ]
机构
[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLL STN,TX 77843
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 11期
关键词
D O I
10.1021/j100113a007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
When H2O and O2, together with either H-2 or D2, were passed over a heated Pt wire, the variation in E(a) with respect to the O2/(H-2 or D2) ratio was the same. This result is taken as evidence that the Pt-OH bond strength is affected by the coverage of oxygen on the surface, rather than by the effect of temperature on the hydrogen atom coverage.
引用
收藏
页码:2505 / 2506
页数:2
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