HYDROGEN-ATOM ABSTRACTION REACTIONS IN ORGANIC-SYNTHESIS - A FORMAL TOTAL SYNTHESIS OF RACEMIC PODOPHYLLOTOXIN

被引：37

作者：

KRAUS, GA

WU, YS

机构：

[1] Department of Chemistry, Iowa State University, Ames

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 10期

关键词：

D O I：

10.1021/jo00036a030

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The key step in a synthesis of 1 was a tandem photoenolization/Diels-Alder reaction to produce 11. Hydrolysis of the acetal and ester followed by oxidation afforded 15, an advanced intermediate in the Meyers synthesis of 1.

引用

页码：2922 / 2925

页数：4

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