FORMATION OF ALUMINUM(III)-MONOCARBOXYLATES IN AQUEOUS-SOLUTION

被引：5

作者：

POHLMEIER, A

THESING, U

KNOCHE, W

机构：

来源：

BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1993年 / 97卷 / 01期

关键词：

CHEMICAL KINETICS; COMPLEX COMPOUNDS; SOLUTIONS;

D O I：

10.1002/bbpc.19930970103

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By means of stopped-flow experiments equilibrium and rate constants are determined for the weak complexation of the aluminium(III)-ion with formate, acetate, chloroacetate and benzoate. For the inner-sphere complex formation both equilibrium and rate constants depend on the nature of the ligand, and a linear free energy relation is observed between rate constants and dissociation constants of the corresponding acids.

引用

页码：10 / 15

页数：6

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