PREPARATION AND ELECTROCHEMICAL REDUCTION OF NITRO SUBSTITUTED METHYL ALKANEDITHIOATES

被引：1
作者：
WOLLNY, B
VOSS, J
机构：
[1] Institut für Organische Chemie der Universität Hamburg, D-2000 Hamburg 13
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 71卷 / 1-4期
关键词：
METHYL NITROALKANEDITHIOATES; POLAROGRAPHY; CYCLOVOLTAMMETRY; PREPARATIVE ELECTROREDUCTION; INTRAMOLECULAR CYCLIZATION;
D O I：
10.1080/10426509208034516
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Methyl nitroalkanedithioates 3 were prepared from the corresponding carboxylic acids 1 and Davy's reagent 2 or, 3e, from 2-nitro-propane, carbon disulfide and iodomethane. Electrochemical reduction of these dithioesters leads to ketene S,S-acetals 4 and oximes 5. In addition, carbocyclic oximes 6 are formed. The latter and related elimination products 14 are also obtained by conventional routes.
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收藏
页码：231 / 243
页数：13
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