POLY(PHENYLENEVINYLENE) BEARING BUILT-IN TERT-BUTYLNITROXIDE - A POLYRADICAL FERROMAGNETICALLY COUPLED IN THE INTRACHAIN

被引：41

作者：

KANEKO, T ^{[1
]}

TORIU, S ^{[1
]}

KUZUMAKI, Y ^{[1
]}

NISHIDE, H ^{[1
]}

TSUCHIDA, E ^{[1
]}

机构：

[1] WASEDA UNIV, DEPT POLYMER CHEM, TOKYO 169, JAPAN

来源：

CHEMISTRY LETTERS | 1994年 / 11期

关键词：

D O I：

10.1246/cl.1994.2135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(1,4- or 1,2-phenylenevinylene)s bearing a 2- or 4-substituted nitroxide radical were synthesized by polymerizing [bromo[N-tert-butyl-N-(trialkylsiloxy)amino]]-styrenes with a palladium catalyst. The polyradicals were chemically stable, and their ESR and SQUID measurements indicated an intramolecular and through-bond ferromagnetic coupling.

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页码：2135 / 2138

页数：4

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