ADDITION OF TETRACHLOROMETHANE TO TRIFLUOROETHENE CATALYZED BY COPPER-COMPLEXES

被引：9

作者：

KOTORA, M

HAJEK, M

机构：

[1] Institute of Chemical Process Fundamentals, Czechoslovak Academy of Sciences, 165 02 Prague 6, Suchdol

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 55卷 / 01期

关键词：

D O I：

10.1016/S0022-1139(00)81253-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of tetrachloromethane to trifluoroethene catalyzed by copper complexes gives 1:1 adducts in up to 97% yield under mild reaction conditions. The catalytic activity and the regioselectivity of copper, ruthenium and palladium complexes and dibenzoyl peroxide have been compared. Differences in regioselectivity indicate that the copper-coordinated trichloromethyl radical is involved in copper-assisted addition reactions, whilst free-radical species in an uncomplexed form play a role in other cases.

引用

页码：57 / 62

页数：6

共 23 条

[1]

[Anonymous], 1970, FREE RADICAL CHAIN R

[2] TELOMERIZATION OF TETRAFLUOROETHYLENE WITH CARBON-TETRACHLORIDE BY REDOX CATALYSIS [J].