THE ROLE OF ALPHA-HYDROGEN ELIMINATION-REACTIONS IN THE FORMATION OF ETA-3-CYCLOPROPENYL-MOLYBDENUM AND ETA-4-CYCLOPENTADIENE-MOLYBDENUM COMPLEXES

被引：17
作者：
FEHER, FJ
GREEN, M
ORPEN, AG
机构：
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1986年 / 04期
关键词：
D O I：
10.1039/c39860000291
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
引用
收藏
页码：291 / 293
页数：3
相关论文
共 12 条
[1]   REACTIONS OF COORDINATED LIGANDS .24. THE REACTION OF BIS(BUT-2-YNE)CARBONYL(ETA-CYCLOPENTADIENYL OR ETA-5-INDENYL)MOLYBDENUM TETRAFLUOROBORATE WITH ACETONITRILE AND PHOSPHINES - CRYSTAL-STRUCTURES OF BUT-2-YNECARBONYL(ETA-5-INDENYL)(TRIETHYLPHOSPHINE)MOLYBDENUM TETRAFLUOROBORATE AND BUT-2-YNE(ETA-5-INDENYL)BIS(TRIMETHYLPHOSPHINE)MOLYBDENUM TETRAFLUOROBORATERU [J].
ALLEN, SR ;
BAKER, PK ;
BARNES, SG ;
GREEN, M ;
TROLLOPE, L ;
MANOJLOVICMUIR, L ;
MUIR, KW .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (03) :873-883
[2]   REACTIONS OF COORDINATED LIGANDS .33. MONONUCLEAR ETA-2-VINYL COMPLEXES - SYNTHESIS, STRUCTURE, AND REACTIVITY [J].
ALLEN, SR ;
BEEVOR, RG ;
GREEN, M ;
NORMAN, NC ;
ORPEN, AG ;
WILLIAMS, ID .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (03) :435-450
[3]   THE REACTIONS OF AN AMBIDENT LITHIUM MOLYBDENUMVINYLIDENE COMPLEX WITH ELECTROPHILES - NOVEL FORMATION OF A 1,3-DIENE COMPLEX AND EVIDENCE FOR INTRAMOLECULAR CARBON-HYDROGEN ACTIVATION ON PHOTOLYSIS OF A CARBYNE COMPLEX [J].
BEEVOR, RG ;
FREEMAN, MJ ;
GREEN, M ;
MORTON, CE ;
ORPEN, AG .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (02) :68-70
[4]  
CHURCHILL MR, 1983, ORGANOMETALLICS, V2, P1046, DOI 10.1021/om50002a020
[5]   MECHANISM OF ZIEGLER-NATTA POLYMERIZATION OF ACETYLENE - A NUTATION NMR-STUDY [J].
CLARKE, TC ;
YANNONI, CS ;
KATZ, TJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (26) :7787-7789
[6]  
CLAUSON L, 1985, J AM CHEM SOC, V107, P3377
[7]   MECHANISM FOR STEREOSPECIFIC POLYMERIZATION OF OLEFINS BY ZIEGLER-NATTA CATALYSTS [J].
IVIN, KJ ;
ROONEY, JJ ;
STEWART, CD ;
GREEN, MLH ;
MAHTAB, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (14) :604-606
[8]   PREPARATION AND REACTION DYNAMICS OF (ETA-4-C5H6)RE(PPH3)2H3 - A STRUCTURALLY CHARACTERIZED ETA-4-CYCLOPENTADIENE COMPLEX [J].
JONES, WD ;
MAGUIRE, JA .
ORGANOMETALLICS, 1985, 4 (05) :951-953
[9]   REACTION OF TUNGSTEN(VI) ALKYLIDYNE COMPLEXES WITH ACETYLENES TO GIVE TUNGSTENACYCLOBUTADIENE AND TUNGSTEN CYCLOPENTADIENYL COMPLEXES [J].
PEDERSEN, SF ;
SCHROCK, RR ;
CHURCHILL, MR ;
WASSERMAN, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (24) :6808-6809
[10]  
SCHROCK RR, 1983, ACS SYM SER, V211, P369
12